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Ultrashort laser modification of transparent materials: synergy of excitation/relaxation kinetics, thermodynamics and mechanics

机译:透明材料的超短激光改性:激发/弛豫动力学,热力学和力学的协同作用

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摘要

Ultrafast laser modification of transparent materials is an important technique enabling production of 3D photonic structures whose practical applications are rapidly widening. The physics behind laser-induced modifications is extremely rich and involves a variety of consecutive processes initiated by radiation absorption during the laser pulse and extending to millisecond timescales when the final structure becomes "frozen" in the material matrix. The quality of the final structures depends of the synergetic action of excitation of confined electron plasma, its relaxation with drawing matter into different thermodynamic states from soft heating to extreme conditions, generation of GPa pressures resulting in shock-induced material deformations, re-forming of covalent bonds upon photo-excitation of the material network. In this report, we will review the physical processes responsible for various forms of laser-induced modification in wide-bandgap materials, including volume nanograting formation. We will present the modeling results obtained on the basis of the Maxwell's equations supplemented with equations describing the dynamics of the laser-induced electron plasma on the example of silica glass for typical experimental conditions. The temperature and associated stress levels are mapped in the laser energy absorption zone which may be foreseen at the end of electron - glass matrix relaxation, enabling to make conclusions on the routes of glass modification. Finally, the energy balance is considered, matching the free electron density and temperature with several threshold values (melting, plastic deformation, material failure with void formation, sublimation).
机译:透明材料的超快激光改性是一项重要的技术,可用于生产3D光子结构,其实际应用正在迅速扩展。激光诱导的修饰背后的物理学非常丰富,涉及各种连续过程,这些过程由激光脉冲期间的辐射吸收引发,并在最终结构在材料矩阵中“冻结”时扩展到毫秒级。最终结构的质量取决于密闭电子等离子体激发的协同作用,其松弛作用以及将物质从软加热到极端条件的拉伸转变为不同的热力学状态,产生GPa压力导致冲击引起的材料变形,材料的重新形成物质网络的光激发产生共价键。在本报告中,我们将回顾负责宽带隙材料中各种形式的激光诱导改性的物理过程,包括体积纳米光栅的形成。我们将介绍在麦克斯韦方程组基础上获得的建模结果,并在典型实验条件下以石英玻璃为例,描述了激光诱导的电子等离子体的动力学方程。温度和相关应力水平在激光能量吸收区中绘制,这可以在电子-玻璃基质弛豫结束时预见,从而可以得出有关玻璃改性途径的结论。最后,考虑能量平衡,使自由电子密度和温度与几个阈值(熔化,塑性变形,具有空洞形成的材料破坏,升华)相匹配。

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